Associate Professor
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Enantioselective H‐Bond‐Directing Approach for Trienamine‐mediated Reactions in Asymmetric Synthesis
Ł Albrecht, F Cruz Acosta, A Fraile, A Albrecht, J Christensen, ...
Angewandte Chemie International Edition 51 (36), 9088-9092, 2012
Organocatalytic transformations of alkynals, alkynones, propriolates, and related electron-deficient alkynes
A Fraile, A Parra, M Tortosa, J Aleman
Tetrahedron 48 (70), 9145-9173, 2014
Expanding the Scope of Arylsulfonylacetylenes as Alkynylating Reagents and Mechanistic Insights in the Formation of Csp2 Csp and Csp3 Csp Bonds from Organolithiums
JL García Ruano, J Alemán, L Marzo, C Alvarado, M Tortosa, ...
Chemistry-A European Journal 18 (27), 8414-8422, 2012
The Role of Steric and Electronic Interactions in the Stereocontrol of the Asymmetric 1, 3-Dipolar Reactions of 5-Ethoxy-3-p-(S)-tolylsulfinylfuran-2 (5 H)-ones with …
JLG Ruano, A Fraile, G González, MR Martín, FR Clemente, R Gordillo
The Journal of organic chemistry 68 (17), 6522-6534, 2003
Control of the dual reactivity (iminium-dienamine) of β-arylmethyl α, β-unsaturated aldehydes in organocatalytic 1, 3-dipolar cycloadditions with N-benzoyl C, N-cyclic …
C Izquierdo, F Esteban, A Parra, R Alfaro, J Aleman, A Fraile, JLG Ruano
The Journal of organic chemistry 79 (21), 10417-10433, 2014
Enantioselective Synthesis of 4‐Isoxazolines by 1, 3‐Dipolar Cycloadditions of Nitrones to Alkynals Catalyzed by Fluorodiphenylmethylpyrrolidines
J Alemán, A Fraile, L Marzo, JLG Ruano, C Izquierdo, S Díaz‐Tendero
Advanced Synthesis & Catalysis 354 (9), 1665-1671, 2012
Methyl Sulfinates as Electrophiles in Friedel–Crafts Reactions. Synthesis of Aryl Sulfoxides
F Yuste, A Hernandez Linares, VM Mastranzo, B Ortiz, ...
The Journal of organic chemistry 76 (11), 4635-4644, 2011
Intramolecular hydrogen bond activation: Thiourea-organocatalyzed enantioselective 1, 3-dipolar cycloaddition of salicylaldehyde-derived azomethine ylides with nitroalkenes
F Esteban, W Cieślik, EM Arpa, A Guerrero-Corella, S Díaz-Tendero, ...
ACS catalysis 8 (3), 1884-1890, 2018
Arylsulfonylacetylenes as alkynylating reagents of Csp2-H bonds activated with lithium bases.
JL Ruano, J Alemán, L Marzo, C Alvarado, M Tortosa, S Díaz-Tendero, ...
Angewandte Chemie (International ed. in English) 51 (11), 2712-2716, 2012
Totally regio-and stereoselective behavior of mono-and diactivated cyclic alkenes in the Lu reaction: synthesis of enantiopure functionalized cyclopentanes
JL García Ruano, A Núñez, Jr, M Rosario Martin, A Fraile
The Journal of organic chemistry 73 (23), 9366-9371, 2008
Thiol–ene/oxidation tandem reaction under visible light photocatalysis: synthesis of alkyl sulfoxides
A Guerrero-Corella, AM Martinez-Gualda, F Ahmadi, E Ming, A Fraile, ...
Chemical Communications 53 (75), 10463-10466, 2017
Asymmetric synthesis of pyrrolo [2, 1-a] isoquinoline derivatives by 1, 3-dipolar cycloadditions of stabilized isoquinolinium N-ylides with sulfinyl dipolarophiles.
JL Ruano, A Fraile, MR Martín, G González, C Fajardo, AM Martín-Castro
The Journal of Organic Chemistry 76 (9), 3296-3305, 2011
Abnormal Behaviour of Allenylsulfones under Lu’s Reaction Conditions: Synthesis of Enantiopure Polyfunctionalised Cyclopentenes
A Núñez Jr, MR Martín, A Fraile, JL García Ruano
Chemistry-A European Journal 16 (18), 5443-5453, 2010
Development and application of asymmetric organocatalytic Mukaiyama and vinylogous Mukaiyama-type reactions
M Frías, W Cieślik, A Fraile, A Rosado-Abón, AF Garrido-Castro, F Yuste, ...
Chemistry-A European Journal, 2018
1, 3-dipolar cycloadditions of diazoalkanes to activated sulfoxides: Influence of lewis acids
JL García Ruano, MT Peromingo, M Alonso, A Fraile, MR Martín, A Tito
The Journal of organic chemistry 70 (22), 8942-8947, 2005
Arylsulfonylacetylenes as Alkynylating Reagents of C H Bonds Activated with Lithium Bases
JL Garcia Ruano, J Aleman, L Marzo, C Alvarado, M Tortosa, ...
Angewandte Chemie International Edition 51 (11), 2712-2716, 2012
The Role of the Sulfinyl Group on the Course of the Reactions of 3-p-Tolylsulfinylfuran-2 (5 H)-ones with Nitrones. Synthetic Uses of Cycloreversion Processes
JL García Ruano, A Fraile, AM Martín Castro, MR Martin
The Journal of organic chemistry 70 (22), 8825-8834, 2005
Pyrrolo [2, 1-b] thiazole Derivatives by Asymmetric 1, 3-Dipolar Reactions of Thiazolium Azomethine Ylides to Activated Vinyl Sulfoxides
JL García Ruano, A Fraile, MR Martín, G González, C Fajardo
The Journal of organic chemistry 73 (21), 8484-8490, 2008
Organophosphorus Reagents in Organocatalysis: Synthesis of Optically Active α‐Methylene‐δ‐lactones and δ‐Lactams
A Albrecht, F Morana, A Fraile, KA Jørgensen
Chemistry–A European Journal 18 (33), 10348-10354, 2012
Asymmetric 1, 3-dipolar reactions of 3-sulfinylfuran-2 (5H)-ones with 11H-dibenzo [b, e] azepine 5-oxide. Synthesis of pyrroloazepines via isoxazoloazepines
JLG Ruano, JIA Gil, A Fraile, AMM Castro, MR Martı́n
Tetrahedron letters 45 (24), 4653-4656, 2004
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